• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to a process for preparing a detergent solution, a detergent solution and a method for cleaning surfaces containing impurities. The detergent solution contains at least one liquid, such as water, as portion capsules mixed for human and animal harmless bacterial preparations, such as probiotics. The water used is advantageously tap water from which substances which kill bacteria in said bacterial preparation and advantageously also all or nearly all salts are removed.
    公开号:FI20185343A1
    申请号:FI20185343
    申请日:2018-04-10
    公开日:2019-05-14
    发明作者:Mikko Haapsaari；Esko Aulanko；Timo Kaarlela
    申请人:Emp Innovations Oy；OmaSiivous Oy；Linda Clean Oy；
    IPC主号:
    专利说明:

    METHOD FOR PREPARING THE CLEANING SOLUTION, THE CLEANING SOLUTION AND THE CLEANING OF SUBJECT MATTER
    Field of the Invention
    The invention relates to a process for the preparation of a detergent solution as defined in the preamble of claim 1, to a cleaning solution as defined in the preamble of claim 5 and to a method for the purification of contaminated objects as defined in the preamble of claim 12.
    Background of the Invention
    The solution according to the invention is directed to non-toxic cleaning and cleaning. Commonly used detergents, hereinafter referred to as "detergents", consist of a variety of different raw materials and burden the environment at all stages of its life cycle. Ingredients that affect the detergent's cleaning performance are called active ingredients, and ingredients that affect shelf life, appearance, and fragrance are called excipients. Cleaner raw materials are often oil-based, which are non-renewable resources.
    For this reason, the use and disposal of state-of-the-art cleaning agents causes emissions to water, air and soil. In addition, some of the active ingredients in cleaning chemicals are toxic and can accumulate in organisms and become rich in food chains. The chemicals also contain eutrophicating ingredients in waterways.
    Chemicals-based cleaners also have effects on human health. Man may be exposed to cleaning chemicals by mouth, skin and by inhalation, either directly or indirectly via the environment. In addition, humans may also be exposed to cleaning chemicals from food. Because not all chemicals in detergents decompose in the wastewater treatment process, chemicals accumulate in water, groundwater and further into drinking water and human food such as fish. Another problem with chemicals is that their use leads to the development of more resistant microbial strains.
    In the prior art, various chlorine compounds are used as one chemical ingredient in detergents, in particular disinfectant cleaners. The problem with using such cleansers is that they are corrosive to the skin and irritating to the eyes and can even be harmful to the eyes. They may also release gases, may cause symptoms of allergy or asthma or breathing difficulties when inhaled. In addition, cleaning and disinfectants containing chlorine compounds are harmful to the environment.
    Allergies as well as odors of chemical sensitivities have increased and knowledge about them has also increased.
    This is one of the reasons why the cleaning industry is beginning to look for ways to reduce the use of chemicals in cleaning products. Thus, one of the prior art chemical-free rat25 scrubbers has begun to use ot20185343 prh 10 -04-2018 sonicated oxidant, water, as a cleaning agent.
    yes
    The ozone it is very reactive is very effective at killing
    For this reason, however, the problem with ozone, and powerful microbes.
    that it is also very dangerous to health and also damages everyone
    With ozone, organic surfaces.
    responds well with which you are sensitive to the respiratory tract almost anything it comes into contact with.
    when it does, it reacts anytime
    Thus, the exemplary cellular fat20185343 prh 10 -04-2018, proteins, etc., which damages or kills cells.
    When inhaled, ozone depresses lung function, damages lung tissue and causes cough and dyspnea. Other symptoms associated with high levels of ozone include burning and redness of the eyes, irritation of the nose and throat, fatigue, malaise and headache. Allergy symptoms can also get worse during high ozone levels. Particularly sensitive to ozone-induced irritation are asthmatics and infants.
    Studies have shown that up to 3% of people in Europe die from ozone pollution already caused by traffic emissions. With ozonated water cleaning, exposure to cleaners and cleaning facilities is tens, even hundreds of times greater than that caused by traffic. However, the adverse effects of ozonated water on cleaning are minimized and justified, inter alia, by the short duration of exposure to cleaning. Exposure is therefore shorter for other people in the cleaning area, but the cleaners themselves are easily exposed for up to eight hours a day. However, studies have shown that very short-term exposure to high concentrations of ozone causes severe health hazards. The problem with recognizing ozone deaths and diseases is that the diseases are lung diseases for which it is impossible to determine the root cause. Thus, diseases and Deaths are not recorded as ozone.
    Another problem with using ozonated water for cleaning is that the ozone content of the water is diluted very quickly, so it may happen that the cleaning ability of ozonated water is reduced to such an extent that the removal of impurities begins to require more
    20185343 prh 10 -04- 2018 mechanical removal. This means, for example, the need to scrub the surfaces to be cleaned with greater force. However, greater use of force is more onerous for the person carrying out the cleaning work.
    Because of the above drawbacks and disadvantages, less harmful and non-toxic cleaners have been developed. One promising development has been the use of bacteria that are harmless to humans and animals as the active ingredient in cleaning products10. In such cases, the use of probiotics as active substances has generally been reported.
    In these prior art solutions, the active ingredients containing the spore-retained bacteria are in the form of a liquid 15-packed container and containers of various sizes, such as bottles and ampoules. Concentrated fluids containing bacterial spores packaged in this way are called, for example, probiotic concentrates.
    The problem with prior art probiotic concentrates is to dispense them and to ensure the functionality of the probiotic bacteria, i.e., to keep the bacteria dispersible in a solution of probiotic concentrate. When a cleaning agent is used, the probiotic concentrate is dosed to prepare a cleaning solution for use in water. The purity of the water used is usually not set, so the water used, for example ordinary tap water, may contain antimicrobial ingredients such as chlorine and ozone. In this case, the bacteria present in the probiotic concentrate, or at least some of them, die in the prepared detergent solution at a substantially rapid rate, whereby the cleaning result obtained with the detergent solution is not as desired.
    20185343 prh 10 -04- 2018
    It is also a problem that the probiotic spores in the probiotic concentrate in the prepared detergent solution become functional and divergent bacteria only after receiving the appropriate nutrients. Probiotic spores for the purposes of this application are spores of probiotic bacteria. These tap nutrients are often inadequate in tap water, so performance is achieved only when the detergent solution is applied to the surface to be cleaned, and even if surface 10 is provided with suitable nutrients. Thus, the use of prior art probiotic concentrates does not provide reliable and consistent cleaning results. In addition, liquid probiotic concentrates have a very limited lifetime and cannot be stored for long periods. This places great demands on their logistics.
    In addition, one problem with prior art probiotic cleansers is that the bacterial spores stored in the probiotic concentrate are produced using various toxins, usually biocides. The biocides used are strong poisons and thus ruin the whole idea of non-toxic cleaning, that is, non-toxicity itself.
    Summary of the Invention
    It is an object of the present invention to overcome the above drawbacks and to provide an inexpensive and simple method for the preparation of a substantially non-toxic detergent solution. It is a further object of the invention to provide an inexpensive, chemical-free and as non-toxic detergent solution which has good cleaning and disinfecting efficacy and which does not cause any health or environmental damage. Another object is to provide a solution of detergent which is used as an active ingredient for harmless bacteria for humans and animals. The object of the invention is
    20185343 prh 10 -04-2018 also provide a health safe, environmentally friendly and easy-to-use method for cleaning contaminated objects.
    The process for the preparation of a cleaning solution according to the invention is characterized by what is stated in the characterizing part of claim 1. Correspondingly, the detergent solution according to the invention is characterized in what is stated in the characterizing part of claim 5.
    Further, the method of purifying objects containing impurities according to the invention is characterized by what is disclosed in the characterizing part of claim 12.
    Other embodiments of the invention are characterized by what is set forth in the other claims.
    In order to carry out the object of the invention, to prepare a cleaning solution containing bacterial preparations which are harmless to humans and animals, the method according to the invention comprises mixing said bacterial preparations with a liquid. Preferably, said bacterial preparations are then mixed with water in dosage capsules containing bacterial spores and bacterial nutrients.
    Preferably, the detergent solution of the invention contains at least a liquid, harmless to humans and animals, bacterial preparations which comprise bacterial spores packaged in dosage capsules together with bacterial nutrients. Preferably, said liquid is also water from which the bactericidal ingredients and, suitably, all salts have been removed from the said bacterial preparations. Preferably, the nutrients of said bacteria are packaged in dosage capsules together with the bacterial spores, and the shell of the dosage capsules is also arranged to serve as a nutrient for said bacteria.
    20185343 prh 10 -04- 2018
    Preferably, the water used is tap water purified and / or demineralized water using one or more of the following steps: ak5 dense carbon treatment, chemicals, reverse osmosis, ion exchange, UV disinfection, oxidation of organic compounds.
    An advantage of the solution according to the invention is, inter alia, that the detergent solution is a chemical-free solution. In this case, the detergent solution used according to the invention does not cause any allergic symptoms or health problems in humans. In addition, the detergent solution is environmentally friendly. When demineralized water, which has been substantially free of all salts, is used as a liquid in the cleaning solution, no mineral stains remain on the cleaned surfaces after drying. Another advantage is that, due to the non-toxic nature of the detergent solution according to the invention, the use of the detergent solution does not contribute to the development of bacterial strains more resistant.
    Another advantage is that since the bacterial spores used are freeze-dried in closed dose capsules, the bacterial spores have good shelf life, which also facilitates logistics. A further advantage is that, because of the nourishment of bacterial bacteria in the dosage capsules and capsule shells, they are rapidly transformed into efficient dividing bacteria, even when they come into contact with water intended for solution in the preparation of the detergent solution. In this case, the detergent solution applied to the object to be cleaned acts quickly and efficiently. Another advantage is that the dose capsules do not require a large volume.
    Detailed Description of the Invention
    20185343 prh 10 -04- 2018
    The use of bacteria that are harmless to humans and animals, such as probiotics, for cleaning purposes is known per se. Probiotics effectively remove dirt and grease from surfaces to be cleaned. The potency of probiotics is based on the fact that, unlike traditional cleaning, which attempts to kill the microbes of the surfaces to be cleaned with toxins, good microbes are applied to the surfaces in this case, for example probiotic bacteria, whereby bacteria take up living space from harmful microbes. After a while, harmful microbes have disappeared.
    The detergent solution according to the invention is a non-chemical solution which, at its simplest, comprises only demineralized water mixed with bacteria which are harmless to humans and animals, such as probiotics. Demineralized water, as used herein, means water that has at least been eliminated with ingredients that kill bacteria that are harmless to humans and animals. Preferably, all salts have also been removed as accurately as possible from said water.
    Preferably the water used is tap water. Because tap water generally contains chlorine as an ingredient, such water must be purified, for example, demineralized before mixing with bacterial spores, such as probiotic spores. Otherwise, chlorine will kill the mixed bacteria or at least weaken their effectiveness.
    Preferably, the components that kill non-human and animal harmless bacteria, such as probiotics, have been removed from the water used in the cleaning solution by activated carbon, chemicals and / or reverse osmosis. In addition, substantially all or nearly all salts are removed from the water used in the cleaning solution by reverse osmosis
    20185343 prh 10 -04-2018 and / or ion exchange. The water used in the detergent solution according to the invention contains less than 20 ppm, preferably less than 5 ppm, of salts or salt minerals in the preparation of the detergent solution.
    The non-human and non-human bacteria used in the cleaning solution according to the invention are packaged in dosage capsules together with the nutrients of said bacteria. The nutrient is preferably, for example, lactose. In addition, the shell of the capsules serves as a nourishment for said bacteria. The shell is preferably, for example, gelatin. The bacteria are contained within the capsules as spores, preferably freeze-dried spores, which are resistant to extreme conditions for a long time. In addition, various fillers may be contained within the dosage capsules. Preferably, within the dosage capsule, the excipient is an agent that enhances the cleaning effect of the detergent solution. One such substance is, for example, sodium carbonate or soda.
    The detergent solution according to the invention contains the aforementioned purified water in which a desired number of the aforementioned dosage capsules are dissolved. The shell of the dose capsules placed in said purified water dissolves in water and the bacterial spores inside the capsules as well as the nutrients and possibly also the excipients come into contact with said water during the dissolution step. Thereby, the bacterial spores become active, dividing into proliferating bacteria, and receiving a high amount of nutrition inside the capsule and dissolving the shell, the bacterial strain rapidly increases, making the detergent solution effective.
    According to the method of the invention, the above-mentioned cleaning agent solution is prepared by mixing a bacterial preparation containing harmless bacteria for humans and animals in water in dosage capsules containing bacterial spores and bacterial nutrients which are dissolved in water so that the nutrient and as bacterial spores become dividing bacteria.
    According to the invention, which are bacterial preparations as mentioned above, for example probiotic spores, preferably one strain or a mixture of several strains of the genus ba10 cillus, it is immersed in water from which the bactericidal salts of said bacterial preparations have been removed.
    ingredients
    In particular, tap water, which, and preferably also all, is preferably made with water, is utilized with one or more of the following demineralized water: active carbon treatment, chemicals, ion exchange, UV disinfection, organic reverse osmosis, oxidation of compounds.
    20185343 prh 10 -04- 2018
    The detergent solution mixed in the above manner may be used for several days. Preferably, however, the detergent solution is prepared by mixing the probiotic mixture with demineralized, substantially room temperature, tap water just before or shortly before use of the detergent solution.
    Similarly, the method of the invention for purifying contaminant-containing targets comprises contacting the area to be cleaned with a detergent solution 30 containing at least bacterial spores and their nutrients harmless to humans and animals mixed with water having the bactericidal ingredients of said bacterial preparations removed. Said bacterial spores are, for example, probiotic spores, preferably one strain of Bacillus or a mixture of several strains.
    20185343 prh 10 -04- 2018
    Preferably, the area / site / subject to be cleaned is contacted with a solution of detergent containing at least bacterial spores 5 and their nutrients harmless to humans and animals mixed with water having the bactericidal ingredients and / or salts of said bacterial preparations removed by one or more of the following steps: activated carbon treatment, chemicals, reverse osmosis, ion exchange, UV disinfection, oxidation of organic compounds, or contacting the area / site / subject to be purified with a detergent solution containing at least bacterial spores and their nutrients harmless to humans and animals mixed with demineralized water. Preferably, the water used is demineralized tap water.
    The cleaning solution and method according to the invention can be used to clean different surfaces and objects of different sizes and also different textiles.
    In practice, the cleaning of smaller surfaces is effected, for example, by: 1) mixing in a spray bottle a detergent solution according to the invention comprising bacterial preparations harmless to humans and animals, such as probiotics and demineralized water, i.e. water free of bactericidal ingredients and substantially all salts; 2) spraying the detergent solution onto the surfaces to be cleaned; 3) sprayed surfaces are wiped with a clean cloth, preferably with a microfiber cloth.
    Similarly, larger surfaces, such as floors, are cleaned as follows: 1) demineralized water and bacterial preparations that are harmless to humans and animals, such as probiotics, are mixed with water as a cleaning agent.
    20185343 prh 10 -04-2018 to a container such as a cotton ball or bucket; 2) moistening a cleaning device, such as a mop or the like, with a cleaning solution in a water container; 3) wipe the surfaces to be cleaned with a damp / wet cleaner.
    Larger surfaces are also preferably cleaned with a combination machine for cleaning, which generally has its own clean water tank for washing water and a scrub brush or similar surface cleaning element. During cleaning, a suitable detergent solution according to the invention is prepared by mixing a desired number of dose-containing capsules of bacterial preparations that are harmless to humans and animals with demineralized water in a clean water tank to obtain the desired mixture ratio. The composite machine may also have an automatic detergent dispenser 15, whereupon the detergent solution is prepared automatically.
    After cleaning contaminated objects, cleaning agents that are harmless to humans and animals, such as probiotics, such as cleaning cloths, mops, scrubbing brushes, or the like, are washed with water to remove non-human bacterial preparations, such as probiotics. Preferably, said cleaning means are washed with activated charcoal treatment and / or reverse osmosis with demineralized tap water.
    The temperature of the wash water is, for example, about +60 to +95 ° C, preferably about +80 to +90 ° C. The aforementioned cleaning means 30 are washed, for example, in a washing machine. Usually no detergent is used, but if a detergent is desired, so-called detergent is used. black soap.
    Also, any cleaning agent used in the cleaning of the invention, such as the above-mentioned cleaning agents in direct contact with the object to be cleaned, is cleaned with demineralized water according to the above after cleaning.
    It will be apparent to one skilled in the art that various embodiments of the invention are not limited to the examples above, but may vary within the scope of the following claims. It is essential that the solution is prepared and used in a chemical-free detergent solution which combines well-known bacterial preparations harmless to humans and animals, such as probiotics, with the most bacterial-friendly water in the dosage form.
    It is also essential that said bacterial preparations which are harmless to humans and animals are preserved as bacterial spores in sachets together with the nutrient they require and / or that the shell of the sachets is a nutrient suitable for bak20.
    权利要求:
    Claims (16)
    [1]
    1. A process for the preparation of a cleaning solution containing bacterial preparations which are harmless to humans and animals.
    5, wherein said bacterial preparations are mixed with a liquid, characterized in that said bacterial preparations are mixed with the liquid in dosage capsules containing bacterial spores and bacterial nutrients.
    [2]
    A method according to claim 1, characterized in that said bacterial preparations containing probiotic spores packaged in dosage capsules, preferably one strain of Bacillus or a mixture of several strains,
    15 is mixed with water, preferably tap water, from which the bactericidal ingredients of said bacterial preparations have been removed.
    [3]
    Method according to claim 1 or 2, characterized
    20, wherein the bactericidal ingredients and / or substantially all of the salts of said bacterial preparations are removed from the water by activated carbon, chemicals and / or reverse osmosis, and then said bacterial preparations are mixed with water thus purified.
    20185343 prh 10 -04- 2018
    [4]
    4. A process as claimed in any one of claims 1 to 3, characterized in that the cleaning agent solution is made from demineralized water using one or more of them: activated carbon treatment, chemicals, ion exchange, UV disinfection, organic cleaning.
    of the following is silenced osmosis, compounds of acid15
    20185343 prh 10 -04- 2018
    [5]
    A detergent solution containing at least a mixture of bacterial preparations, harmless to humans and animals, mixed with the liquid, characterized in that said bacterial preparations comprise bacterial spores packed in a dose
    5 together with the nutrients of the bacteria, and that the liquid is the water from which the bactericidal ingredients of the said bacterial preparations have been removed.
    [6]
    The cleaning solution according to claim 5, wherein
    It is noted that the nutrients of said bacteria are packaged in dosage capsules together with bacterial spores.
    [7]
    A detergent solution according to claim 5 or 6,
    15 characterized in that the capsule shell is arranged to serve as a nutrient for said bacteria.
    [8]
    A detergent solution according to claim 5, 6 or 7, characterized in that detergent enhancers and / or other excipients are also packed in the dosage capsules.
    [9]
    A detergent solution according to any one of claims 5 to 8, characterized in that the liquid from which
    25 bacterial components of some bacterial preparations have been removed, there is tap water.
    [10]
    A cleaning solution according to any one of claims 5 to 9, characterized in that said
    The bactericidal ingredients of the formulations have been removed from the liquid by activated carbon, chemicals and / or reverse osmosis, and that substantially all salts have been removed from the liquid, preferably by either reverse osmosis and / or ion exchange.
    20185343 prh 10 -04- 2018
    [11]
    A cleaning solution according to any one of claims 5 to 10, characterized in that the spores of bacteria in said bacterial preparations are probiotic spores,
    Preferably, one strain or a mixture of several strains of the genus Bacillus.
    [12]
    12. Method for the purification of contaminated objects without the use of bacterial
    10 cleansing solution containing roads, wherein the area / site / object to be cleaned is contacted with bacterial preparations which are harmless to humans and animals, characterized in that the cleaning area / site / object is contacted with a cleaning solution containing at least bacterial spores harmless to humans and animals; their nutrients in admixture with a liquid in which the bactericidal constituents of the said bacterial preparations have been removed.
    20
    [13]
    13. The method of claim 12, wherein the area / site / subject to be purified is contacted with a detergent solution containing at least bacterial spores and their nutrients harmless to humans and animals mixed with water having the bactericidal ingredients of said bacterial preparations removed, and that said bacterial spores are probiotic spores, preferably one strain or a mixture of several strains of the genus Bacillus.
    30
    [14]
    Method according to claim 12 or 13, characterized in that the area / site / object to be cleaned is contacted with a solution of detergent containing at least bacterial spores and their nutrients harmless to humans and animals mixed with water having the bactericidal ingredients of said bacterial preparations and / or salts using one or more of the following steps: activated carbon treatment, chemicals, reverse osmosis, ion exchange, UV disinfection,
    Or oxidizing the organic compounds, or contacting the area / site / subject to be purified with a cleaning solution containing at least bacterial spores and their nutrients harmless to humans and animals mixed with demineralized water.
    [15]
    Method according to one of the preceding claims 12 to 14, characterized in that after cleaning the objects containing contaminants, the cleaning agents in contact with the bacteria of said bacterial preparations are washed with water having the bactericidal ingredients of said bacterial preparations removed, substantially + 60 ... + 95 ° C. at a temperature of +80 to +90 ° C.
    [16]
    16. A method according to claim 15, characterized in that after cleaning the objects containing impurities, the cleaning means that have been in contact with the bacteria of said bacterial preparations are washed with activated charcoal treatment and / or reverse osmosis with deminylated water.
    类似技术:
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    同族专利:
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    法律状态:
    2018-10-17| PC| Transfer of assignment of patent|Owner name: GREEN BERRY OY |
    2021-08-31| FG| Patent granted|Ref document number: 129181 Country of ref document: FI Kind code of ref document: B |
    优先权:
    申请号 | 申请日 | 专利标题
    FI20176015A|FI20176015A1|2017-11-13|2017-11-13|Cleaning solution, method for preparing said solution and method for cleaning targets containing impurities|PCT/FI2018/050833| WO2019092324A1|2017-11-13|2018-11-13|Bacterial preparation, a method for preparing a cleaning solution, a cleaning solution, and a method for cleaning dirty targets|
    KR1020207013169A| KR20200083982A|2017-11-13|2018-11-13|Bacterial preparation, manufacturing method of cleaning solution, cleaning solution, and cleaning method of dirty target|
    US16/763,949| US20200362271A1|2017-11-13|2018-11-13|Bacterial preparation, a method for preparing a cleaning solution, a cleaning solution, and a method for cleaning dirty targets|
    FIU20184212U| FI12393U1|2017-11-13|2018-11-13|Bacterial preparation and cleaning solution|
    JP2020526222A| JP2021502106A|2017-11-13|2018-11-13|Bacterial preparations, cleaning solutions, cleaning solutions, and cleaning methods for dirty targets|
    CN201880073449.7A| CN111344387A|2017-11-13|2018-11-13|Bacterial preparation, method for producing a cleaning solution, cleaning solution and method for cleaning dirty objects|
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